Synthesis of (R)- or (S)-diphenylphosphinoyl hydroxy aldehydes and 1,2-diols using Mukaiyama's bicyclic aminal methodology and Sharpless asymmetric dihydroxylation

DOI: 10.1039/p19960002129

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 2129 - 2138 (1996)

Update date:2022-07-30

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Authors:

O'Brien, Peter

Warren, Stuart

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Article abstract of DOI:10.1039/p19960002129

Two different approaches to diphenylphosphinoyl hydroxy aldehydes and 1,2-diols are compared. A lengthy chiral auxiliary approach using proline-derived aminals enables hydroxy aldehydes and 1,2-diols of known absolute stereochemistry and high enantiomeric

Full text of DOI:10.1039/p19960002129

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