Homochiral lithium amides: Enantioselective deprotonation of cyclohexene oxide

Article abstract of DOI:10.1080/00397919408011196

Reaction of cyclohexene oxide with chiral lithium amides has been studied and (S)-2-cyclohexen-1-ol was prepared in 20-82% ee. The optical purity was determined by proton NMR measurement of α-methoxy-α- (trifluoromethyl)phenylacetic acid (MTPA) derivative of the corresponding alcohol.

Full text of DOI:10.1080/00397919408011196

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Synthetic Communications: An
International Journal for Rapid
Communication of Synthetic
Organic Chemistry
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Homochiral Lithium Amides:
Enantioselective Deprotonation
of Cyclohexene Oxide
Debnath Bhuniya a & Vinod K. Singh a
a Department of Chemistry , Indian Institute of
Technology , Kanpur, India , 208 016
Published online: 23 Sep 2006.
To cite this article: Debnath Bhuniya & Vinod K. Singh (1994) Homochiral
Lithium Amides: Enantioselective Deprotonation of Cyclohexene Oxide, Synthetic
Communications: An International Journal for Rapid Communication of Synthetic
Organic Chemistry, 24:3, 375-385
To link to this article: http://dx.doi.org/10.1080/00397919408011196
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