Oxymetalation of Khellin. Solvomercuration, Osmylation, and Palladium-Catalyzed Oxidation of the Furan Ring in Khellin. The Synthesis of Highly Oxygenated Chromones and 2-Substituted Furochromones

DOI: 10.1021/jo00366a007

Source and publish data:

Journal of Organic Chemistry p. 3116 - 3123 (1986)

Update date:2022-09-26

Topics:

Authors:

Gammill, Ronald B.

Nash, Sharon A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00366a007

Oxidation of khellin with thallium(III) nitrate (TTN) in methanol results in the addition of two molecules of methanol across the 2,3-double bond in the furan ring.Oxidation of khellin with mercuric(II) nitrate (Hg(NO3)2) in aqueous THF followed by treatm

Full text of DOI:10.1021/jo00366a007

Products guided by the article

Product name:2-benzoyl-3-methyl-4,8-dimethoxybenzo<1,2-b:5,4-b>difuran-2,6-dione

Cas No:102830-32-0

R&D Labs maybe for 102830-32-0

Eastar Chemical Corporation

website:http://www.eastarchem.com/

Contact:1-800-898-2436

Address:1215 K Street, STE 1700
Chengdu Yunyi International Trade Co., Ltd

Contact:

Address:china
Esuccess Material Limited

Contact:852-29282288

Address:HONGKONG
YanCheng LongShen Chemical Co.,Ltd.

Contact:+86-515-86668866

Address:No.13,Weiyi Road,Funing Aoyang Industrial Park
Xinji City Taida Sinopec Co., Ltd.

Contact:0086-311-85341278

Address:No.6, Nanhua Road,Xinji City Road,Hebei Province,China

Relevant to this article

Development of paramagnetic probes for molecular recognition studies in protein kinases

Doi:10.1021/jm800068w
(2008)
Novel 16-membered macrolides modified at C-12 and C-13 positions of midecamycin A₁ and miokamycin. Part 1: Synthesis and evaluation of 12,13-carbamate and 12-arylalkylamino-13-hydroxy analogues

Doi:10.1016/j.bmc.2008.01.027
(2008)
Preparation and Crystal Structure of <2(μ-N2)>

Doi:10.1039/c39820001291
(1982)
Methyl (11aS)-1,2,3,5,11,11a-hexahydro-3,3-dimethyl-1-oxo-6H-imidazo- [3′,4′:1,2]pyridin[3,4-b]-indol-2-substituted acetates: Synthesis and three-dimensional quantitative structure-activity relationship investigation as a class of novel vasodilators

Doi:10.1021/jm800249j
(2008)
Total synthesis of (-)-corilagin

Doi:10.1021/ja803111z
(2008)
Discovery and structure-activity relationship studies of 2-benzylidene-2,3-dihydro-1H-inden-1-one and benzofuran-3(2H)-one derivatives as a novel class of potential therapeutics for inflammatory bowel disease

Doi:10.1016/j.ejmech.2017.06.018
(2017)

Article Doi