Oxymetalation of Khellin. Solvomercuration, Osmylation, and Palladium-Catalyzed Oxidation of the Furan Ring in Khellin. The Synthesis of Highly Oxygenated Chromones and 2-Substituted Furochromones

DOI: 10.1021/jo00366a007

Source and publish data:

Journal of Organic Chemistry p. 3116 - 3123 (1986)

Update date:2022-09-26

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Authors:

Gammill, Ronald B.

Nash, Sharon A.

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Article abstract of DOI:10.1021/jo00366a007

Oxidation of khellin with thallium(III) nitrate (TTN) in methanol results in the addition of two molecules of methanol across the 2,3-double bond in the furan ring.Oxidation of khellin with mercuric(II) nitrate (Hg(NO3)2) in aqueous THF followed by treatm

Full text of DOI:10.1021/jo00366a007

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