Journal of Organic Chemistry p. 3859 - 3870 (1995)
Update date:2022-08-02
Topics: Precursor Radical Cyclization Stereocontrolled Synthesis Dienes
Gomez, Ana M.
Lopez, J. Cristobal
Fraser-Reid, Bert
A new strategy for the synthesis of Woodward's densely functionalized carbocyclic precursor to reserpine (2) that is based upon serial radical 5-exo/6-exo cyclizations of readily prepared dienic hexopyranose derivatives has been examined.The substrates 4,
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