Control of Regiospecificity in Ionic Diels-Alder Reactions. The Use of Allylic Alcohols and Allylic Ethers as Precursors of Dienophilic Allyl Cations

DOI: 10.1021/jo00365a048

Source and publish data:

Journal of Organic Chemistry p. 3075 - 3076 (1986)

Update date:2022-08-03

Topics:

Authors:

Gassman, Paul G.

Singleton, Daniel A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00365a048

Allylic alcohols and allylic ethers have been used as precursors of allyl cations in an intramolecular "ionic Diels-Alder reaction" in order to gain complete control of the regiochemistry of the cycloaddition.

Full text of DOI:10.1021/jo00365a048

Products guided by the article

Product name:1-[2-((E)-4-Methyl-hexa-3,5-dienyl)-[1,3]dithian-2-yl]-3-phenyl-cyclohex-2-enol

Cas No:102871-04-5

R&D Labs maybe for 102871-04-5

YanCheng LongShen Chemical Co.,Ltd.

Contact:+86-515-86668866

Address:No.13,Weiyi Road,Funing Aoyang Industrial Park
Wuxi Zuping Food Science And Technology Co.,LTD.

Contact:+86-510-87210822

Address:Guanlin town
Shanghai Bosman Industrial Co., Ltd

Contact:86-21-63065878-8006

Address:Rm907, No.1611, North Sichuan Road, Hongkou District, Shanghai, 200080 China
Shaanxi Lighte Optoelectronics Material Co., Ltd.

Contact:+86-29-88320728-622/619/620

Address:No.55 INDUSTRY ROAD 2,XI'AN NATIONAL CIVIL AEROSPACE INDUSTRIAL PARK.XI'AN China 710065.
A.M FOOD CHEMICAL CO., LIMITED

Contact:86-531-87100375

Address:20Floor，Bblock，1Building，pharma-valley，Jinan，China

Relevant to this article

Synthesis and Properties of Alkyl β-d-Galactopyranoside

Doi:10.1007/s11743-016-1865-0
(2016)
Synthesis of novel analogues of (+)-varitriol via olefin cross-metathesis reaction

Doi:10.1016/j.bmcl.2008.02.062
(2008)
Preparation and analgesic activity of (-)-11α-substituted 1,2,3,4,5,6-hexahydro-6α,7-(methyleneoxy)-2,6-methano-3-ben zazocines

Doi:10.1021/jm00160a022
(1986)
The synthesis, characterization and polymerization behavior of ansa cyclopentadienyl fluorenyl complexes; the X-ray structures of the complexes [(C₁₃H₈)SiR₂(C₅H ₄)]ZrCl₂ (R = Me or Ph)

Doi:10.1016/0022-328X(95)05788-Q
(1996)
A Convergent Carbohydrate Approach to the Synthesis of Taxol. Part 2. Ring C Subunit

Doi:10.1016/0040-4039(95)00272-E
(1995)
Design and synthesis of potent dual inhibitors of JAK2 and HDAC based on fusing the pharmacophores of XL019 and vorinostat

Doi:10.1016/j.ejmech.2018.09.024
(2018)

Article Doi