Control of Regiospecificity in Ionic Diels-Alder Reactions. The Use of Allylic Alcohols and Allylic Ethers as Precursors of Dienophilic Allyl Cations

DOI: 10.1021/jo00365a048

Source and publish data:

Journal of Organic Chemistry p. 3075 - 3076 (1986)

Update date:2022-08-03

Topics:

Authors:

Gassman, Paul G.

Singleton, Daniel A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00365a048

Allylic alcohols and allylic ethers have been used as precursors of allyl cations in an intramolecular "ionic Diels-Alder reaction" in order to gain complete control of the regiochemistry of the cycloaddition.

Full text of DOI:10.1021/jo00365a048

Products guided by the article

Product name:1-[2-((E)-4-Methyl-hexa-3,5-dienyl)-[1,3]dithian-2-yl]-3-phenyl-cyclohex-2-enol

Cas No:102871-04-5

R&D Labs maybe for 102871-04-5

Tianjin Te-An Chemtech Co., Ltd.(expird)

Contact:+86-22-65378638

Address:A5-8, No.80 Haiyun Street, TEDA
Shanghai Bocimed Pharmaceutical Co., Ltd.

website:http://www.bocimed.com

Contact:+86-21-68861632

Address:Building 1, Lane 647, Songtao Road, Zhangjiang High-Tech Park, Shanghai
Taizhou Shengxing Chempharm Co.,Ltd

Contact:+86-576-88516600

Address:Yantou Chemical Zone Jiaojiang Taizhou Zhejiang China
Shouguang Nuomeng Chemical Co., Ltd.

Contact:+86-536-5119508/18363669993

Address:Hou Zhen Industrial Park, Shouguang, Shandong, China
Fuxin Jintelai Fluorin Chemical Co., Ltd.

Contact:+86-0418-8229599

Address:, 7th Huagong Road, Fluorine industry development zone (Yimatu Town,Fumeng County),Fuxin City, Liaoning Province, China

Relevant to this article

Synthesis and Properties of Alkyl β-d-Galactopyranoside

Doi:10.1007/s11743-016-1865-0
(2016)
Synthesis of novel analogues of (+)-varitriol via olefin cross-metathesis reaction

Doi:10.1016/j.bmcl.2008.02.062
(2008)
Preparation and analgesic activity of (-)-11α-substituted 1,2,3,4,5,6-hexahydro-6α,7-(methyleneoxy)-2,6-methano-3-ben zazocines

Doi:10.1021/jm00160a022
(1986)
The synthesis, characterization and polymerization behavior of ansa cyclopentadienyl fluorenyl complexes; the X-ray structures of the complexes [(C₁₃H₈)SiR₂(C₅H ₄)]ZrCl₂ (R = Me or Ph)

Doi:10.1016/0022-328X(95)05788-Q
(1996)
A Convergent Carbohydrate Approach to the Synthesis of Taxol. Part 2. Ring C Subunit

Doi:10.1016/0040-4039(95)00272-E
(1995)
Design and synthesis of potent dual inhibitors of JAK2 and HDAC based on fusing the pharmacophores of XL019 and vorinostat

Doi:10.1016/j.ejmech.2018.09.024
(2018)

Article Doi