Control of Regiospecificity in Ionic Diels-Alder Reactions. The Use of Allylic Alcohols and Allylic Ethers as Precursors of Dienophilic Allyl Cations

DOI: 10.1021/jo00365a048

Source and publish data:

Journal of Organic Chemistry p. 3075 - 3076 (1986)

Update date:2022-08-03

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Authors:

Gassman, Paul G.

Singleton, Daniel A.

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Article abstract of DOI:10.1021/jo00365a048

Allylic alcohols and allylic ethers have been used as precursors of allyl cations in an intramolecular "ionic Diels-Alder reaction" in order to gain complete control of the regiochemistry of the cycloaddition.

Full text of DOI:10.1021/jo00365a048

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