Bulletin of the Chemical Society of Japan p. 1001 - 1005 (1995)
Update date:2022-07-30
Topics:
Yao, Jiachang
Yonehara, Hisatomo
Pac, Chyongjin
High-yield synthesis of pure oxo(phthalocyaninato)titanium(IV) was conveniently achieved by heating a mixture of 1,2-dicyanobenzene, titanium(IV) butoxide, urea, and 1-octanol at 150 deg C.It is suggested that a key pathway of the efficient condensation reaction is the complex formation of titanium(IV) butoxide with ammonia generated by the nucleophilic attack of 1-octanol to urea.Applicabilities of this method were investigated for condensation reactions of 1,2-dicyanobenzene with other metal alkoxides.
Contact:+86 021-51698675
Address:1701, Jielong Plaza, No.618 Pingliang Rd, ShangHai,China
JiangXi Keyuan Biopharma Co., LTD.
Contact:+86-563-6833666
Address:Guangde Fine Chemical Zone, Anhui Province, China
Contact:+86-(0)21-3770 9035
Address:Room 301, Building 2, Meijiabang Road 1508, Shanghai China
Contact:+86-021-58123769
Address:No.780 of Cailun Road,Zhangjiang Hi-tech Park,Pudong,Shanghai
Contact:+86-570-4336358
Address:No.87 Building,Tianqian,Sidu Town
Doi:10.1002/ejoc.200701011
(2008)Doi:10.1002/chem.200701411
(2008)Doi:10.1021/ja01490a041
(1960)Doi:10.1016/j.tetlet.2007.07.075
(2007)Doi:10.1021/ja01571a062
(1957)Doi:10.1002/ardp.19562890503
(1956)
