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Synthesis of β-Hydroxy Nitriles via Indium-Induced Coupling of Bromoacetonitrile with Carbonyl Compounds

DOI: 10.1246/bcsj.67.1126

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1126 - 1129 (1994)

Update date:2022-08-05

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Authors:

Araki, ShukiAraki, Shuki

Yamada, MasafumiYamada, Masafumi

Butsugan, YasuoButsugan, Yasuo

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Article abstract of DOI:10.1246/bcsj.67.1126

The organoindium reagent, derived from indium metal and bromoacetonitrile, reacted with carbonyl compounds in the presence of chlorotrimethylsilane to give, after hydrolysis, β-hydroxy nitriles.The coupling proceeded with high chemoselectivity, though the diastereoselectivity was low.

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Full text of DOI:10.1246/bcsj.67.1126

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