Bulletin of the Chemical Society of Japan p. 1126 - 1129 (1994)
Update date:2022-08-05
Topics:
Araki, Shuki
Yamada, Masafumi
Butsugan, Yasuo
The organoindium reagent, derived from indium metal and bromoacetonitrile, reacted with carbonyl compounds in the presence of chlorotrimethylsilane to give, after hydrolysis, β-hydroxy nitriles.The coupling proceeded with high chemoselectivity, though the diastereoselectivity was low.
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