Preparation of Metallacyclosulphones of Nickel, Palladium, and Platinum and the X-Ray Crystal Structure of trans-2,4-Diphenyl-1,1-bis(triphenylarsine)platinathietane-3,3-dioxide

DOI: 10.1039/c39860000041

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 41 - 42 (1986)

Update date:2022-09-26

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Authors:

Chiu, Kwok W.

Fawcett, John

Henderson, William

Kemmitt, Raymond D. W.

Russel, David R.

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Article abstract of DOI:10.1039/c39860000041

A variety of metallathietane-3,3-dioxide of platinum(II), palladium(II), and nickel(II), are formed in high yield by the action of the dianion (PhCHS(O)2CHPh>(2-) upon either cis- or trans-; the X-ray structure of the title compound (1a) establishes the presence of a puckered platinathietane-3,3-dioxide ring with no substantial Pt...S transannular bonding.

Full text of DOI:10.1039/c39860000041

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