Cobalt Carbonyl Catalyzed Hydrosilylation of Nitriles: A New Preparation of N,N-Disilylamines

DOI: 10.1021/jo00289a014

Source and publish data:

Journal of Organic Chemistry p. 449 - 453 (1990)

Update date:2022-07-30

Topics:

Authors:

Murai, Toshiaki

Sakane, Takehiko

Kato, Shinzi

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Article abstract of DOI:10.1021/jo00289a014

Cobalt carbonyl catalyzed hydrosilylation of a wide variety of nitriles with HSiMe3 has been examined.The reaction generally proceeded at 60 deg C to give N,N-disilylamines in good yields.Electron-donating groups on aromatic nitriles facilitated the react

Full text of DOI:10.1021/jo00289a014

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