Cobalt Carbonyl Catalyzed Hydrosilylation of Nitriles: A New Preparation of N,N-Disilylamines

DOI: 10.1021/jo00289a014

Source and publish data:

Journal of Organic Chemistry p. 449 - 453 (1990)

Update date:2022-07-30

Topics:

Authors:

Murai, Toshiaki

Sakane, Takehiko

Kato, Shinzi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00289a014

Cobalt carbonyl catalyzed hydrosilylation of a wide variety of nitriles with HSiMe3 has been examined.The reaction generally proceeded at 60 deg C to give N,N-disilylamines in good yields.Electron-donating groups on aromatic nitriles facilitated the react

Full text of DOI:10.1021/jo00289a014

Products guided by the article

Product name:[4-(1,1,1,3,3,3-Hexamethyl-disilazan-2-ylmethyl)-phenyl]-acetonitrile

Cas No:103560-19-6

R&D Labs maybe for 103560-19-6

Shanghai Xinda Pharmaceuticals Co., Ltd.

Contact:86-21-33692333-8008

Address:999 Linxian Road, Jinshan Industrial Park, Shanghai, China
Joyochem Co., Ltd.

website:http://www.joyochem.com

Contact:0531-82687998

Address:Factory Building 11, Jinan Comprehensive free trade zone, Shandong, China
Yuan Shi(SuQian)Biotechnology Co.,Ltd

website:http://www.yuanshibio.com

Contact:+86-527-84226672

Address:jiangsu suqian
Nanjing Fayekong Chemcial Co.,Ltd(expird)

Contact:86-25-58813444

Address:Rm 1503, Unit 1, Building 5, Zijinnanyuan, Nanjing, Jiangsu, China
ZiBO KuoDing Trade company Ltd

website:http://www.sdzbkd.com

Contact:86-13361591822

Address:GongQingTuan road

Relevant to this article

Discovery and SAR of orally efficacious tetrahydropyridopyridazinone PARP inhibitors for the treatment of cancer

Doi:10.1016/j.bmc.2012.06.021
(2012)
From Methaqualone and Beyond: Structure - Activity Relationship of 6-, 7-, and 8-Substituted 2,3-Diphenyl-quinazolin-4(3H)-ones and in Silico Prediction of Putative Binding Modes of Quinazolin-4(3H)-ones as Positive Allosteric Modulators of GABA_A

Doi:10.1021/acschemneuro.0c00600
(2020)

Efficient Metallo-Ene Reactions in Organoaqueous Phase

Doi:10.1021/ol016023f
(2001)
Synthesis and structure-activity relationship studies of small molecule disruptors of EWS-FLI1 interactions in Ewing's sarcoma

Doi:10.1021/jm501372p
(2014)
Doi:10.1021/ja01309a053
(1935)
Synthesis of 1,8-Dioxo-decahydroacridine Derivatives via Ru-Catalyzed Acceptorless Dehydrogenative Multicomponent Reaction

Doi:10.1021/acs.joc.1c01075
(2021)

Article Doi