Chemistry of Heterocyclic Compounds p. 1034 - 1039 (1985)
Update date:2022-09-26
Topics:
Dovgilevich, A. V.
Zelenin, K. N.
Espenbetov, A. A.
Struchkov, Yu. T.
Bezhan, I. P.
et al.
It was shown by x-ray diffraction analysis and PMR spectroscopy that 1-acyl-5-hydroxy- and -5-hydrazinopyrazolidines have a conformation with an axial orientation of the functional group attached to the C(5) atom.The 1-salicylyl derivatives constitute an exception: in methanol solutions they exist in a conformation with an equatorial hydroxy group, whereas in dimethylformamide (DMF) the ring undergoes partial opening to give the corresponding β-hydrazido aldehydes.
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Doi:10.1021/jo01116a612
(1956)Doi:10.1016/S0040-4039(00)94983-9
(1985)Doi:10.1021/jf800651z
(2008)Doi:10.1002/chem.200900231
(2009)Doi:10.1002/poc.4171
(2021)Doi:10.1016/j.carres.2008.05.004
(2008)
