Conformations of Saturated Six-Membered-Ring Phosphorus Heterocycles Related to Cyclophosphamide. NMR, X-ray, and Infrared Studies of 2-Methoxy-2-oxo-1,3,2-oxazaphosphorinane and 2-Thio-1,3,2-oxazaphosphorinane

DOI: 10.1021/ja00281a037

Source and publish data:

Journal of the American Chemical Society p. 6669 - 6675 (1986)

Update date:2022-08-04

Topics:

Authors:

Bentrude, Wesley G.

Setzer, William N.

Sopchik, Alan E.

Bajwa, Gurdip S.

Burright, Donald D.

Hutchinson, John P.

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Article abstract of DOI:10.1021/ja00281a037

The conformations of a series of 2-methoxy-2-oxo- and 2-thio-1,3,2-oxazaphosphorinanes have been investigated.The methoxy substituent on phosphorus causes 5,5-dimethyl-substituted derivatives to populate almost exclusively a chair conformation with MeO ax

Full text of DOI:10.1021/ja00281a037

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