Tetrahedron p. 5443 - 5450 (1986)
Update date:2022-09-26
Topics:
Annunziata, Rita
Cinquino, Mauro
Cozzi, Franco
Raimondi, Laura
Stefanelli, Stefania
Reaction of allyl sulphinyl anion with chiral α-methylaldehydes affords α- or γ-adducts in highly regiocontrolled fashion, depending on reaction conditions.From the α-adducts syn (E)-2-alkene-1,4-diols are obtained as major (d.r. 2:1 <*> 28:1) products by thiophile promoted desulphurization.
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Doi:10.1080/00397911.2020.1843178
(2021)Doi:10.1080/07328300802030845
(2008)Doi:10.1021/acs.joc.0c00061
(2020)Doi:10.1016/S0040-4020(01)87431-7
(1986)Doi:10.1016/S0040-4039(00)84132-5
(1986)Doi:10.1016/j.ejmech.2008.04.012
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