STEREOSELECTIVE SYNTHESIS OF (E)-2-ALKENE-1,4-DIOLS VIA METALLATED ALLYLIC SULPHOXIDES

DOI: 10.1016/S0040-4020(01)82095-0

Source and publish data:

Tetrahedron p. 5443 - 5450 (1986)

Update date:2022-09-26

Topics:

Authors:

Annunziata, Rita

Cinquino, Mauro

Cozzi, Franco

Raimondi, Laura

Stefanelli, Stefania

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)82095-0

Reaction of allyl sulphinyl anion with chiral α-methylaldehydes affords α- or γ-adducts in highly regiocontrolled fashion, depending on reaction conditions.From the α-adducts syn (E)-2-alkene-1,4-diols are obtained as major (d.r. 2:1 <*> 28:1) products by thiophile promoted desulphurization.

Full text of DOI:10.1016/S0040-4020(01)82095-0

Products guided by the article

Product name:2-Cyclohexyl-4-(toluene-4-sulfinyl)-hex-5-en-3-ol

Cas No:103867-63-6

R&D Labs maybe for 103867-63-6

PharmaResources(Kaiyuan)CO,.Ltd

Contact:+86-21-50720028

Address:No.3, Beihuan Road, Economic Development District, Kaiyuan City, Tieling City, Liaoning Province, China 112300
Jiangxi Dongxu Chemical Science & Technology Co.,Ltd

Contact:+86-791-86899381

Address:Nanchang, Jiangxi, China
Sarchem Laboratories, Inc.

Contact:732.938.2777

Address:5012 Industrial Road Farmingdale, NJ 07727
Phantom-pharma

Contact:

Address:
Zhejiang kehong chemical co., ltd

Contact:0086-575-85522000

Address:xiner center RD binhai industrial zone shaoxing zhejiang province P.R.China,312073

Relevant to this article

One-pot, two-step synthesis of 7-methylene-1,5-piperazine-fused 1,2,3-triazoles

Doi:10.1080/00397911.2020.1843178
(2021)
Improved preparation of β-D-ManNAc-(1→4)-D-Glc and β-D-TalNAc-(1→4)-D-Glc disaccharides and evaluation of their activating properties on the natural killer cells NKR-P1 and CD69 receptors

Doi:10.1080/07328300802030845
(2008)
Acyloxy Rearrangement-Triggered Regioselective Hydration of ?-Acetoxy-α,β-Alkynoates/Halo Alkynes

Doi:10.1021/acs.joc.0c00061
(2020)
ENHANCEMENT OF OPTICAL PURITY OF A PRODUCT BY REMOVING UNWANTED DIASTEREOMERS IN THE COURSE OF A CHIRAL SYNTHESIS: NEW SYNTHESIS OF THE STEREOISOMERS OF 2,8-DIMETHYL-1,7-DIOXASPIRO<5.5>UNDECANE, THE PHEROMONE OF ANDRENA WILKELLA

Doi:10.1016/S0040-4020(01)87431-7
(1986)
CARBENIC REACTIONS OF 4-DIAZO-4H-IMIDAZOLE WITH BENZENE DERIVATIVES

Doi:10.1016/S0040-4039(00)84132-5
(1986)
Design, synthesis and characterization of N₉/N₇-substituted 6-aminopurines as VEGF-R and EGF-R inhibitors

Doi:10.1016/j.ejmech.2008.04.012
(2009)

Article Doi