
Tetrahedron p. 4495 - 4502 (1985)
Update date:2022-09-26
Topics:
Callot, H. J.
Metz, F.
The stereochemical course of the cyclopropanation of Z-olefins by ethyl diazoacetate in the presence of various binuclear rhodium(II)carboxylates was studied.The highest syn/anti ratio (up to <*> 3) was obtained using Rh2(O2CR)3(O2CR') where R = 2,4,6-triarylphenyl and R' = CH3 or CF3.
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(2008)