β-Deuterium Secondary Isotope Effects in Heterolytic Decarboxylation Reactions. Manifestations of Negative Hyperconjugation

DOI: 10.1021/jo00371a010

Source and publish data:

Journal of Organic Chemistry p. 3964 - 3968 (1986)

Update date:2022-07-31

Topics:

Authors:

Kluger, Ronald

Brandl, Michael

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00371a010

Although β-deuterium kinetic isotope effects have been recognized as useful probes of transition-state strucutures in cabanion-forming reactions, measurements of these effects in heterolytic decarboxylation reactions have not previously been reported.In t

Full text of DOI:10.1021/jo00371a010

Products guided by the article

Product name:tert-butyl 2,2,bis(perdeuteriomethyl)benzoylacetate

Cas No:104015-37-4

R&D Labs maybe for 104015-37-4

Shijiazhuang Frontierchem Co., Ltd.

Contact:+86-311-89271196

Address:4-4-202 No.15 Biandian Street,Shijiazhuang
Anhui Sholon New Material Technology Co., Ltd.

website:http://www.sholonchem.com

Contact:+86-550-5261666

Address:4/F Block B, Beijing Chemical Building.No.520 Tianrun Road ,Science & Education Town Wujin District, Changzhou City Jiangsu Province
Zhejiang Chemicals Import & Export Corporation (ZHECHEM)

Contact:+86-571-87046953

Address:No. 37, Qingchun Road
BAODING SINO-CHEM INDUSTRY CO.,LTD

Contact:0312-5956088

Address:NO.8 FUXING ROAD,CHINA
Shenzhen Feiming Science and Technology Co,. Ltd

Contact:+86-755-85232577

Address:#B2309, Fenglin International Center ,Jixiang Road, Longcheng street, LongGang District, Shenzhen city, Guangdong province, China.

Relevant to this article

Synthesis, structure, and transport property of perfluorinated oligofluorenes

Doi:10.1002/chem.200800406
(2008)
Evidence from mechanistic probes for distinct hydroperoxide rearrangement mechanisms in the intradiol and extradiol catechol dioxygenases

Doi:10.1021/ja8029569
(2008)
Rapid Enantioselective and Diastereoconvergent Hybrid Organic/Biocatalytic Entry into the Oseltamivir Core

Doi:10.1021/acs.joc.1c00326
(2021)
Synthesis of anthraquinone oligonucleotides for triplex stabilization

Doi:10.1080/15257770701506491
(2007)
Facile synthesis of ortho-pyridyl-substituted corroles and molecular structures of analogous porphyrins

Doi:10.1016/j.tetlet.2008.04.113
(2008)
Aerobic Photooxidative Synthesis of β-Alkoxy Monohydroperoxides Using an Organo Photoredox Catalyst Controlled by a Base

Doi:10.1002/asia.201701742
(2018)

Article Doi