β-Deuterium Secondary Isotope Effects in Heterolytic Decarboxylation Reactions. Manifestations of Negative Hyperconjugation

DOI: 10.1021/jo00371a010

Source and publish data:

Journal of Organic Chemistry p. 3964 - 3968 (1986)

Update date:2022-07-31

Topics:

Authors:

Kluger, Ronald

Brandl, Michael

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00371a010

Although β-deuterium kinetic isotope effects have been recognized as useful probes of transition-state strucutures in cabanion-forming reactions, measurements of these effects in heterolytic decarboxylation reactions have not previously been reported.In t

Full text of DOI:10.1021/jo00371a010

Products guided by the article

Product name:tert-butyl 2,2,bis(perdeuteriomethyl)benzoylacetate

Cas No:104015-37-4

R&D Labs maybe for 104015-37-4

Jai Radhe Sales

website:http://www.jairadhesales.com

Contact:0091-79-26431096

Address:309 Harikrupa Tower,Nr old Sharda Mandir Char Rasta,Ellisbridge
Shanghai doly chemical Co.,Ltd

Contact:+86-21-34716221

Address:No.328,WuHe Roard,MinHang,ShangHai China
Zipont chem(wuhan）Tech co.，Ltd

Contact:+86-27-87587198

Address:wuhan
ShanDong XinDa Chemical CO.,LTD(expird)

Contact:086-0311-87580543

Address:No.168, High Technology Development Zone Jinan Shandong China
Shandong Hongxiang Zinc Co., Ltd

Contact:086-0311-66187879

Address:DaWang developing zone

Relevant to this article

Synthesis, structure, and transport property of perfluorinated oligofluorenes

Doi:10.1002/chem.200800406
(2008)
Evidence from mechanistic probes for distinct hydroperoxide rearrangement mechanisms in the intradiol and extradiol catechol dioxygenases

Doi:10.1021/ja8029569
(2008)
Rapid Enantioselective and Diastereoconvergent Hybrid Organic/Biocatalytic Entry into the Oseltamivir Core

Doi:10.1021/acs.joc.1c00326
(2021)
Synthesis of anthraquinone oligonucleotides for triplex stabilization

Doi:10.1080/15257770701506491
(2007)
Facile synthesis of ortho-pyridyl-substituted corroles and molecular structures of analogous porphyrins

Doi:10.1016/j.tetlet.2008.04.113
(2008)
Aerobic Photooxidative Synthesis of β-Alkoxy Monohydroperoxides Using an Organo Photoredox Catalyst Controlled by a Base

Doi:10.1002/asia.201701742
(2018)

Article Doi