β-Deuterium Secondary Isotope Effects in Heterolytic Decarboxylation Reactions. Manifestations of Negative Hyperconjugation

DOI: 10.1021/jo00371a010

Source and publish data:

Journal of Organic Chemistry p. 3964 - 3968 (1986)

Update date:2022-07-31

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Authors:

Kluger, Ronald

Brandl, Michael

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Article abstract of DOI:10.1021/jo00371a010

Although β-deuterium kinetic isotope effects have been recognized as useful probes of transition-state strucutures in cabanion-forming reactions, measurements of these effects in heterolytic decarboxylation reactions have not previously been reported.In t

Full text of DOI:10.1021/jo00371a010

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