Tetrahedron Letters p. 4181 - 4182 (1985)
Update date:2022-07-30
Topics:
Boireau, G.
Korenova, A.
Deberly, A.
Abenhaim, D.
Using tetraalkylaluminates prepared via hydroalumination in THF of various vinyl compounds resulted in selective addition to the keto group of phenylglyoxylic acid (-)-menthyl ester.Not only simple alkyl groups but also functionalized alkyl groups were added.By this way, a variety of α-substituted mandelic acid (-)-menthyl esters were obtained with diastereomeric excesses close to 70percent.
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