Reaction of Grignard compounds with 4-chloro-2-methyl-3-butyn-2-ol in Diethyl Ether equivalents

DOI: 10.1023/A:1012348627878

Source and publish data:

Russian Journal of Organic Chemistry p. 5 - 8 (2001)

Update date:2022-07-30

Topics:

Authors:

Shchelkunov

Sivolobova

Mataeva Mataeva

Minbaev Minbaev

Muldakhmetov

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Article abstract of DOI:10.1023/A:1012348627878

Reactions of RMgX · THF complexes with 4-chloro-2-methyl-3-butyn-2-ol in aromatic hydrocarbons were studied. The complexes formed by arylmagnesium halides require the presence of anisole for the reaction to occur. 4-Chloro-2-methyl-3-butyn-2-ol can be synthesized by reaction of 2-methyl-3-butyn-2-ol with sodium hypochloride in the two-phase system water-benzene.

Full text of DOI:10.1023/A:1012348627878

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