Direct Deoxygenation of the Hydroxy Group of Methyl 1-Hydroxyalkyl-(phenyl)-phosphinates using Diphosphorus Tetraiodide

DOI: 10.1055/s-1985-31377

Source and publish data:

Synthesis p. 896 - 897 (1985)

Update date:2022-07-30

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Authors:

Yamashita, Mitsuji

Tsunekawa, Kenji

Sugiura, Motoyuki

Oshikawa, Tatsuo

Inokawa, Saburo

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Article abstract of DOI:10.1055/s-1985-31377

The hydroxy group of methyl 1-hydroxyalkyl-(phenyl)-phosphinates 3, prepared from methyl phenylphosphinate 1 and aldehydes or ketones 2, is directly deoxygenated on treatment with diphosphorus tetraiodide to give the methyl alkyl-(phenyl)-phosphinates 4.

Full text of DOI:10.1055/s-1985-31377

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