RADICAL REARRANGEMENT OF A THIOESTER MEDIATED BY COBALAMIN

DOI: 10.1246/cl.1986.703

Source and publish data:

Chemistry Letters p. 703 - 704 (1986)

Update date:2022-07-30

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Authors:

Tada, Masaru

Inoue, Kunimi

Okabe, Masami

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Article abstract of DOI:10.1246/cl.1986.703

Zinc-reduction of 2-(ethylthio)carbonyl-2-phenylpropyl bromide in the presence of cobalamin gave the products formed by the migration of the thioester group.The formation of olefinic products excludes an anion mechanism and the rearrengement is concluded

Full text of DOI:10.1246/cl.1986.703

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