ASYMMETRIC SYNTHESIS OF (5R,6R)-AEGINETOLIDE AND (5R)-DIHYDROACTINIDIOLIDE FROM (R)-2-HYDROXY-2-METHYLCYCLOHEXANONE

DOI: 10.1246/cl.1985.1391

Source and publish data:

Chemistry Letters p. 1391 - 1392 (1985)

Update date:2022-08-04

Topics:

Authors:

Sato, Toshio

Funabora, Makoto

Watanabe, Makoto

Fujisawa, Tamotsu

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Article abstract of DOI:10.1246/cl.1985.1391

C₁₁-Cyclic terpenes, (5R,6R)-(-)-aeginetolide and (5R)-(-)-dihydroactinidiolide have been synthesized stereoselectively starting from (R)-2-hydroxy-2-methylcyclohexanone in short steps.

Full text of DOI:10.1246/cl.1985.1391

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Product name:(R)-2,2,6-Trimethyl-6-trimethylsilanyloxy-cyclohexanone

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