A REGIO- AND STEREOSELECTIVE SYNTHESIS OF ALDOLIZED γ-DIKETONES VIA TIN(IV) BISENOLATES BY THE USE OF BIS(2-PYRIDINETHYOLATO)TIN(II)

DOI: 10.1246/cl.1985.1539

Source and publish data:

Chemistry Letters p. 1539 - 1542 (1985)

Update date:2022-09-26

Topics: Characterization Purification Work-Up

Authors:

Mukaiyama, Teruaki

Ichikawa, Junji

Toba, Makoto

Hayashi, Masaji

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Article abstract of DOI:10.1246/cl.1985.1539

Tin(IV) bisenolates of γ-diketones, generated regioselectively from α,β-unsaturated γ-diketones by the reaction with bis(2-pyridinethiolato)tin(II), react with aldehydes stereoselectively to afford the corresponding aldolized γ-diketones in good yields.

Full text of DOI:10.1246/cl.1985.1539

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