
Chemistry - A European Journal p. 15239 - 15243 (2019)
Update date:2022-07-29
Topics:
Ashikari, Yosuke
Saito, Kodai
Nokami, Toshiki
Yoshida, Jun-ichi
Nagaki, Aiichiro
The present study describes the cationic oxo-thiolation of polymerizable alkenes by using highly reactive cationic species generated by anodic oxidation. These highly reactive cations were able to activate alkenes before their polymerization. Fast mixing in flow microreactors effectively controlled chemoselectivity, enabling higher reaction temperatures.
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