Tetrahedron p. 5677 - 5683 (1985)
Update date:2022-07-30
Topics:
Fournier
Davoust
Basselier
With Li+ or TBA+ as counter ion the electrodimerization of phenylpent-2-en-3-one occurs by a 0.2 F initiation. This reaction is regio- and stereospecific with Li+, the radical autocatalytic reaction gave 100% yield of a new dimer. If TBA+ is used the primary step is an ion-substrate reaction giving two isomers in equal proportion. All reaction products were structurally determined by 2D-NMR (SECSY or COSY and NOESY sequence).
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(1991)Doi:10.1039/c2jm15868j
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(2012)
