Catalysed Epoxidation and Hydroxylation of Alkene by Osmium(III)-Porphyrin Complexes

DOI: 10.1039/c39860000386

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 386 - 388 (1986)

Update date:2022-07-29

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Authors:

Che, Chi-Ming

Chung, Wai-Cheung

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Article abstract of DOI:10.1039/c39860000386

Osmium(III)-porphyrin complexes have been prepared by Br2 oxidation of Os(II)(P)(P-n-Bu3)(CO) in CH2Cl2 ; the 'Os(III)(P)(P-n-Bu3)Br = PhIO' system is capable of performing epoxidation and hydroxylation of styrene and cyclohexene.

Full text of DOI:10.1039/c39860000386

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Product name:Os(II)(meso-tetraphenylporphinato)(P(n-Bu)3)(CO)

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