Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 106 - 109 (1991)
Update date:2022-07-30
Topics:
Elinson, M. N.
Makhova, I. V.
Nikishin, G. I.
An electrocatalytic haloform reaction is accomplished.Methyl ketones are converted to the corresponding carboxylic acid methyl esters in a diaphragmless electrolyzer in methanol in the presence of catalytic quantities of NaBr.The methyl ester of 3-phenylpropanoic acid is formed from benzyl methyl ketone under these conditions via electrochemically induced Favorskii rearrangement.
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