Asymmetric enamide hydrogenation using phosphinite thioglycosides: Synthesis of D- and L-aminoesters using D-sugars as catalyst precursors

DOI: 10.1021/ol801301x

Source and publish data:

Organic Letters p. 3697 - 3700 (2008)

Update date:2022-08-03

Topics:

Authors:

Khiar, Noureddine

Navas, Raquel

Suarez, Belen

Alvarez, Eleuterio

Fernandez, Inmaculada

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Article abstract of DOI:10.1021/ol801301x

(Chemical Equation Presented) Diastereomerically pure cationic Rh(I) complexes derived from phosphinite thioglycosides I were used as catalysts in highly enantioselective hydrogenations of enamides. The conformational similarity of α-D-arabinopyranose wit

Full text of DOI:10.1021/ol801301x

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