Synthesis of L-Glutamic Acid Stereospecifically Labelled at C-4 with Tritium: Stereochemistry of Tritium Release Catalyzed by the Vitamin K-Dependent Carboxylase in the Absence of Carboxylation

DOI: 10.1039/P19860001323

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 1323 - 1328 (1986)

Update date:2022-08-04

Topics:

Authors:

Ducrocq, Claire

Righini-Tapie, Anne

Azerad, Robert

Green, James F.

Friedman, Paul A.

et al. et al.

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Article abstract of DOI:10.1039/P19860001323

<4-(3)H1>-L-Glutamic acids have been synthesized by reduction of (2S,4S)- and (2S,4R)-N-benzyloxycarbonyl-4-halogenoglutamic acid dimethyl esters with <(3)H4>sodium borohydride in dimethylformamide.The degree of stereospecific labelling differed according

Full text of DOI:10.1039/P19860001323

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