FACILE ACCESS TO METHYL TANTALUM DERIVATIVES BY UNPRECEDENTED PHOSPHOROUS-METHYL BOND CLEAVAGE OF DIMETHYLPHENYLPHOSPHANE

DOI: 10.1016/0022-328X(86)82026-5

Source and publish data:

Journal of Organometallic Chemistry p. C29 - C31 (1986)

Update date:2022-07-30

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Authors:

Hovnanian, Nadine

Hubert-Pfalzgraf, Liliane G.

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Article abstract of DOI:10.1016/0022-328X(86)82026-5

Reaction of the paramagnetic pentacoordinated TaBr3(PhPMe)2 adduct with strong bases, (RLi (R = Me, Bu) or 1,8-bis(dimethylamino)naphthalene) have been found to give methyltantalum(IV) derivatives as a result of P-Me bond cleavage.

Full text of DOI:10.1016/0022-328X(86)82026-5

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