Chemistry of Heterocyclic Compounds p. 1076 - 1079 (1986)
Update date:2022-07-29
Topics:
Shustov, G. V.
Denisenko, S. N.
Chervin, I. I.
Zolotoi, A. B.
D'yachenko, O. A.
et all
X-ray diffraction structural analysis and 13 C and 15 N NMR spectroscopy were used to establish that the final product of the halogenation of 5-acyl-1,6-diazabicyclo<3.1.0>hexane is the oxo-6-halo derivative.Thus, the observed transformation of the initially formed endo-N-chloro isomer is an inversion and not 1,2-acyl migration as previously proposed.
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(1987)
