Tetrahedron p. 2235 - 2242 (1986)
Update date:2022-08-04
Topics:
Enders, Dieter
Rendenbach, Beatrice E. M.
A simple and efficient asymmetric synthesis of the pheromones of the small forest ant (Formica polyctena) and the red wood ant (F. rufa) is described.The key step is an asymmetric Michael addition of lithiated propanal-SAMP- or RAMP-hydrazone to enoates with virtually complete asymmetric induction (de,ee <*>96percent).
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(1952)
