SCHWEFEL(IV)-VERBINDUNGEN ALS LIGANDEN VI. KOORDINATIVE UND OXIDATIVE ADDITION AN QUADRATISCH-PLANARE IRIDIUM-SCHWEFELDIOXID-KOMPLEXE

DOI: 10.1016/0022-328X(86)80244-3

Source and publish data:

Journal of Organometallic Chemistry p. C27 - C30 (1986)

Update date:2022-07-29

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Authors:

Schenk, Wolfdieter A.

Leissner, Johanna

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Article abstract of DOI:10.1016/0022-328X(86)80244-3

The sulfur dioxide complexes Ir(PR3)2Cl(SO2) (R=i-Pr, cyclohexyl) react with CO to give the corresponding carbonyls Ir(PR3)2Cl(CO) via the unstable intermediates Ir(PR3)2Cl(CO)(SO2).With H2 and HCl they form the oxidative-addition products IrH2(PR3)2Cl(SO

Full text of DOI:10.1016/0022-328X(86)80244-3

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