Journal of Organometallic Chemistry p. C27 - C30 (1986)
Update date:2022-07-29
Topics:
Schenk, Wolfdieter A.
Leissner, Johanna
The sulfur dioxide complexes Ir(PR3)2Cl(SO2) (R=i-Pr, cyclohexyl) react with CO to give the corresponding carbonyls Ir(PR3)2Cl(CO) via the unstable intermediates Ir(PR3)2Cl(CO)(SO2).With H2 and HCl they form the oxidative-addition products IrH2(PR3)2Cl(SO
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