AMINO ACID APPROACH AS A GENERAL ROUTE TO NONSTABILIZED AZOMETHINE YLIDES. FACILE GENERATION OF PARENT METHANIMINIUM METHYLIDE AND ITS 1-MONO- AND 1,1-DISUBSTITUTED DERIVATIVES

DOI: 10.1246/cl.1986.973

Source and publish data:

Chemistry Letters p. 973 - 976 (1986)

Update date:2022-07-30

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Authors:

Tsuge, Otohiko

Kanemasa, Shuji

Ohe, Masayuki

Takenaka, Shigeori

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Article abstract of DOI:10.1246/cl.1986.973

Decarboxylative condensation of glycine or N-substituted glycines with a variety of carbonyl compounds such as formaldehyde, aromatic aldehyde, or ketones is a convenient and general route to parent methaniminium and its 1-mono- and 1,1-disubstituted derivatives with or without an N-substituent.

Full text of DOI:10.1246/cl.1986.973

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