Helvetica Chimica Acta p. 2128 - 2131 (1985)
Update date:2022-07-29
Topics:
Dumont, Raymond
Pfander,Hanspeter
Brossi, Arnold
Grewe cyclization of the N-formyl-protected octahydroisoquinolin-6-one 1 prepared by conventional chemistry did not afford the expected homomorphinanone.The exclusive reaction product obtained in good yield was the α,β-unsaturated N-formyloctahydroisoquinolin-6-one 2, further converted by acid hydrolysis into the crystalline octahydroisoquinolin-6-one 8.
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