Tetrahedron p. 2831 - 2846 (1986)
Update date:2022-07-29
Topics:
Funk, Raymond L.
Abelman, Matthew, M.
Munger, John D.
Macrocyclic ketene acetals 3 undergo Claisen rearrangements smoothly and constitute a viable and general approach to hetero- or carbocyclic ring systems 4.This novel ring contraction process is subject to high internal asymmetric induction (cf. lactones 7 -> carbocycles 8) as well as relative asymmetric induction in the rearrangements of ketene acetals derived from lactones 18, 23 and 27.Finally, N-benzoylmeroquinene methyl ester (37) was prepared to demonstrate the potential of this methodology in heterocycle synthesis.
View MoreFusilin chemical science & technology co., ltd.
Contact:532-80698166/86057573, +86-400-669-7885
Address:School of Material Science & Engineering, Shandong Uinversity of Science & Technology, Huangdao Zone, Qindao, Shandong
Hangzhou LINGEBA Technology Co., Ltd.
Contact:+0086-571-87389059
Address:Office 1-913,NewYouth Plaza, GongShu Area, HangZhou,ZheJiang,P.R.China
HANGZHOU TOYOND BIOTECH CO., LTD
Contact:+86-571-86965177
Address:No. 189, Fengqi East Road, Hangzhou, China
Contact:0550-7041128 0550-7090578
Address:Wangdian Street,Xinjie Town
Zouping Fuhai Technology Development Co., Ltd.
Contact:+0532-86934525 18660293207
Address:jiuhu town industrial park Zouping County,bingzhou Provincejiuhu town industrial park
Doi:10.1016/S0040-4039(00)84451-2
(1986)Doi:10.1039/c3ra43989e
(2013)Doi:10.1016/j.bmc.2008.04.023
(2008)Doi:10.1021/ja00278a038
(1986)Doi:10.1021/jo800324c
(2008)Doi:10.1021/ja711447s
(2008)
