Stereoselective synthesis of 1,3-diol from β-hydroxyacylsilane via rearrangement of phenyl group from silicon to carbon

DOI: 10.1016/00404-0399(50)1050R-

Source and publish data:

Tetrahedron Letters p. 5555 - 5558 (1995)

Update date:2022-07-29

Topics:

Authors:

Morihata, Kohdai

Horiuchi, Yoshihiro

Taniguchi, Masahiko

Oshima, Koichiro

Utimoto, Kiitiro

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Article abstract of DOI:10.1016/00404-0399(50)1050R-

Treatment of β-hydroxyacyldimethylphenylsilanes with potassium fluoride in DMSO gave 1,3-diols stereoselectively via migration of phenyl group on silicon.

Full text of DOI:10.1016/00404-0399(50)1050R-

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