Stereoselective synthesis of 1,3-diol from β-hydroxyacylsilane via rearrangement of phenyl group from silicon to carbon

DOI: 10.1016/00404-0399(50)1050R-

Source and publish data:

Tetrahedron Letters p. 5555 - 5558 (1995)

Update date:2022-07-29

Topics:

Authors:

Morihata, Kohdai

Horiuchi, Yoshihiro

Taniguchi, Masahiko

Oshima, Koichiro

Utimoto, Kiitiro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/00404-0399(50)1050R-

Treatment of β-hydroxyacyldimethylphenylsilanes with potassium fluoride in DMSO gave 1,3-diols stereoselectively via migration of phenyl group on silicon.

Full text of DOI:10.1016/00404-0399(50)1050R-

Products guided by the article

Product name:syn,anti-2-Methyl-1,3-diphenylpropan-1,3-diol

Cas No:106565-20-2

R&D Labs maybe for 106565-20-2

Shijiazhuang Frontierchem Co., Ltd.

Contact:+86-311-89271196

Address:4-4-202 No.15 Biandian Street,Shijiazhuang
Tomo Pharma Chem Co., Limited

Contact:+86-158-05817090

Address:ROOM 9F, FLAT 2, GUODU DEVELOPING BLDG, No.182, ZHAOHUI ROAD
Guarson Chemical Co., Ltd.

website:http://www.guarson.com

Contact:+86-523-88059600,+86-13805268803

Address:Room B1006,Yafang Building,Jiangyan Avenue,Jiangyan District, Taizhou City,Jiangsu,China
Changsha Botaniex Inc.

Contact:(86) 731 88718666

Address:Room 1222, Unit 4, Building B, Shangcheng, No.47, Kaiyuan East Road.
NEW FORTUNE INDUSTRIAL CO.,LTD.

website:http://newfortune.lookchem.com/

Contact:+86-25-8645-9456

Address:C4-105 GREEN ISLAND FLOWER TOWN

Relevant to this article

A Janus-Wedge DNA triplex with A-W₁-T and G-W₂-C base triplets

Doi:10.1021/ja804607v
(2008)
Suzuki cross-coupling reaction catalyzed by sulfur-containing palladacycles: Formation of palladium active species

Doi:10.1016/j.molcata.2008.02.015
(2008)
Doi:10.1021/ja00794a600
(1973)
The first tandem acetalization/5-exo-dig cyclization of 6-phenylethynylpyrimidine-5-carbaldehydes: Efficient synthesis of 5-alkoxy-(7Z)-7-benzylidene-5,7-dihydrofuro[3,4-d]pyrimidines

Doi:10.1055/s-2008-1077824
(2008)
Enhanced sialylating activity of O-chloroacetylated 2-thioethyl sialosides

Doi:10.1055/s-2005-868514
(2005)
A novel route towards cycle-tail peptides using oxime resin: Teaching an old dog a new trick

Doi:10.1039/c8ob01868e
(2018)

Article Doi