Journal of Physical Chemistry p. 2211 - 2216 (1987)
Update date:2022-07-29
Topics:
Dominey, Lawrence A.
Comeford, Lorrie
Chen, Steven J.-H.
Grunwald, Ernest
Twenty-two salts of the type p-YC6H4NMe2R(1+) p-XC6H4SO3(1-) were synthesized.R = Me, Et;x = CH3,Cl,Br,NO2; Y = H,Br.These salts exist as ion pair in dilute solutions in octanoic acid.Eight salts were soluble enough to permit measurement of ion-pair dipole moments.Analysis indicates that in the ion pairs, the N(1+) center of the cation is adjacent to one of SO3(1-) oxygen atoms.Preliminary results for infrared S-O streching frequencies in the free anions and ion pairs are consistent with this analysis.A novel concentric spherical dielectric cell is described.
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Doi:10.1039/c39860001568
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