Journal of the American Chemical Society p. 2082 - 2089 (1987)
Update date:2022-08-04
Topics:
Danishefsky, Samuel J.
DeNinno, Shari
Lartey, Paul
The reactions of (E)- and (Z)-crotylsilanes of the type R3Si-CH2-CH=CH-CH3 with activated glycal derivatives in the presence of BF3 etherate have been examined.In all cases, the reactions were regiospecific, resulting in incorporation of a 3-methylprop-1-
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