Catalytic Synthesis of Vinyl Carbamates from Carbon Dioxide and Alkynes with Ruthenium Complexes

DOI: 10.1021/jo00268a008

Source and publish data:

Journal of Organic Chemistry p. 1518 - 1523 (1989)

Update date:2022-08-05

Topics:

Authors:

Mahe, Roger

Sasaki, Yoshiyuki

Bruneau, Christian

Dixneuf, Pierre H.

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Article abstract of DOI:10.1021/jo00268a008

Terminal alkynes react with carbon dioxide and secondary amines in the presence of ruthenium complexes to afford vinyl carbamates in one step.The reaction has been performed with phenylacetylene, hexyne, and acetylene and with dialkylamines, morpholine, p

Full text of DOI:10.1021/jo00268a008

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