Synthetic Communications p. 3345 - 3357 (1998)
Update date:2022-08-03
Topics:
Van Heerden, Fanie R.
Dixon, John T.
Holzapfel, Cedric W.
The synthesis of a steroidal 6-deoxy-α-L-allopyranoside from cholestanol and rhamnose is described. The crucial steps in the reaction sequence comprised the transformation of a pseudoglycal into the more steric hindered 2,3-cisdiol via an intermediate bro
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