Journal of Organic Chemistry p. 1276 - 1280 (1987)
Update date:2022-08-04
Topics: NMR spectroscopy Catalyst Arylation Reaction Conditions Stereospecific Alkenylsilanes
Ikenaga, Kazutoshi
Kikukawa, Kiyoshi
Matsuda, Tsutomu
Alkenyltrimethylsilanes ((E)- and (Z)-RCH=CHSiMe3: R = H, Ph, n-C6H13 and CH3OCH2) stereospecifically reacted at 40 deg C or room temperature with in situ generated phenylpalladium acetate to produce R(Ph)C=CSiMe3 and RCH=C(Ph)SiMe3 with inversion of their geometry.The arylation of CH2=CHSiMe3 with arylpalladium acetates gave (E)-ArCH=CHSiMe3 (Ar = XPH; X = H, 4-Me, 4-MeO, 4-Br, 4-I, 4-EtOCO, and 4-NO2) in good yields.
View MoreContact:+ 86 512 52491118
Address:1 Fuyu Road, Haiyu TownChangshu, Jiangsu, China
SHENYANG COMEBOARD TECHNOLOGY CO., LTD
Contact:+86-24-25724626
Address:Room2210,Tianbao International Building,No.8-1 Weigong South Street,Tiexi District,Shenyang,China
Zhangjiagang Jianing Import & Export Co.,Ltd.
Contact:086-512-55379012 13913607595
Address:NO.1 Guotai North Road Zhangjiagang Economic Development Zone,215600,Jiangsu,China
website:http://www.cheminn.com/
Contact:86-531-67875205
Address:No.9-2,South of Shanda Road, Jinan ,China
Suzhou Tianma Specialty Chemicals Co.,Ltd
Contact:+86-512-68090577
Address:#199, Huayuan Rd, Mudu, Suzhou, Jiangsu, CHINA
Doi:10.1039/C8CC08868C
(2019)Doi:10.1002/anie.200801654
(2008)Doi:10.1016/j.poly.2008.06.027
(2008)Doi:10.1021/acs.orglett.8b00131
(2018)Doi:10.1016/j.tetlet.2014.07.032
(2014)Doi:10.1002/anie.201107919
(2012)
