Stereocontrol in the Intramolecular Diels-Alder Reaction. 7. Use of the Trimethylsilyl Group as a Removable Stereocontrol Element to Provide Greatly Enhanced Levels of Diastereoselection

DOI: 10.1021/jo00218a040

Source and publish data:

Journal of Organic Chemistry p. 3421 - 3423 (1985)

Update date:2022-08-03

Topics:

Authors:

Boeckman, Robert K.

Barta, Thomas E.

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Article abstract of DOI:10.1021/jo00218a040

Introduction of the trimethylsilyl group at defined locations in triene substrates which undergo closure by intramolecular Diels-Alder cycloaddition to both hydrindene and octalin systems results in greatly enhanced levels of diastereoselection

Full text of DOI:10.1021/jo00218a040

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