ACYCLIC STEREOCONTROL BY HETEROCONJUGATE ADDITION--4 ANTI-DIASTEREOSELECTION BY A β-CHELATION EFFECT

DOI: 10.1016/S0040-4020(01)90575-7

Source and publish data:

Tetrahedron p. 2863 - 2872 (1986)

Update date:2022-08-06

Topics:

Authors:

Isobe, Minoru

Ichikawa, Yoshiyasu

Funabashi, Yasunori

Mio, Shigeru

Goto, Toshio

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)90575-7

High selectivity in heteroconjugate addition for C-C bond formation with complete syn-diastereoselection has been attributed to the chelation effect between the α-oxygen atom of the substrate and the nucleophile anions through metal cations.Herein is desc

Full text of DOI:10.1016/S0040-4020(01)90575-7

Products guided by the article

Product name:Dithiocarbonic acid O-[(2R,3S,6S)-2-((S)-2-benzenesulfonyl-1-methyl-ethyl)-6-isopropoxy-tetrahydro-pyran-3-yl] ester S-methyl ester

Cas No:107108-87-2

R&D Labs maybe for 107108-87-2

SINO GREAT ENTERPRISE LTD.

Contact:+86-731-84427351

Address:154 JIANXIANG SOUTH ROAD
zhejiang huangyan wanfeng pharm chem co.ltd

Contact:+86-576- 84160728

Address:No. 5 Dazha Road, Economic,Development Zone(JiangKou), Zhejiang, China
Shanxi Sanwei Group Co.,Ltd

Contact:0086-357-6662688

Address:Zhaocheng town, Hongtong County, Linfen City, Shanxi Province
Jingzhou TianHe Sci&Tech Chemical Co., Ltd.

Contact:86-716-8331612

Address:Jiangjin Road, #18, High-grade technology industries development district, Jingzhou city, Hubei province
shanghai jinshan pharmaceutical Co.,Ltd

Contact:021-57363011，13681638167

Address:No. 7966 Tingfeng Road,Jinshan,Shanghai,China

Relevant to this article

Potent, orally bioavailable, liver-selective stearoyl-CoA desaturase (SCD) inhibitors

Doi:10.1016/j.bmcl.2009.06.017
(2009)
Synthesis and biological activity of 1,3,4-oxa(thia)diazole, 1,2,4-triazole-5-(thio)one and S-substituted derivatives of 3-((2-carboxyethyl)phenylamino)propanoic acid

Doi:10.1007/s11164-015-2290-0
(2016)
Synthesis of D- And L-carbocyclic nucleosides via rhodium-catalyzed asymmetric hydroacylation as the key step

Doi:10.1021/ol801791g
(2008)
Synthesis and reactions of a stable 1,2-diaryl-1,2-dibromodisilene: A precursor for substituted disilenes and a 1,2-diaryldisilyne

Doi:10.1021/ja8061002
(2008)
Synthesis of the C1-C12 fragment of iriomoteolide 1a by sequential catalytic asymmetric vinylogous aldol reactions

Doi:10.1021/ol801940r
(2008)
Chemoselective removal of acyloxy in 1-(benzotriazole-1-yl)alkyl esters and its application in the preparation of β-(benzotriazole-1-yl)alcohols

Doi:10.1080/00397910801993735
(2008)

Article Doi