ACYCLIC STEREOCONTROL BY HETEROCONJUGATE ADDITION--4 ANTI-DIASTEREOSELECTION BY A β-CHELATION EFFECT

DOI: 10.1016/S0040-4020(01)90575-7

Source and publish data:

Tetrahedron p. 2863 - 2872 (1986)

Update date:2022-08-06

Topics:

Authors:

Isobe, Minoru

Ichikawa, Yoshiyasu

Funabashi, Yasunori

Mio, Shigeru

Goto, Toshio

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Article abstract of DOI:10.1016/S0040-4020(01)90575-7

High selectivity in heteroconjugate addition for C-C bond formation with complete syn-diastereoselection has been attributed to the chelation effect between the α-oxygen atom of the substrate and the nucleophile anions through metal cations.Herein is desc

Full text of DOI:10.1016/S0040-4020(01)90575-7

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