Inorganica Chimica Acta p. 169 - 172 (1998)
Update date:2022-08-02
Topics:
Lobana
Sánchez
Casas
García-Tasende
Sordo
The reaction of phenylmercury(II) chloride with acetophenonethiosemicarbazone (Hatsc) in ethanol in 1:1 mole ratio undergoes symmetrisation forming the products, HgCl2(Hatsc)2 and Ph2Hg instead of the anticipated compound PhHgCl(Hatsc). The analytical data, some physical properties, IR and NMR (1H, 13C, 199Hg) spectroscopy all support the formation of HgCl2(Hatsc)2. 199Hg NMR of the solid obtained from the filtrate of the reaction provides evidence for Ph2Hg. This reaction represents the first example of a symmetrisation phenomenon observed in organomercury(II)-thiosemicarbazone chemistry.
Wuhan Soleado Technology Co.,Ltd.
Contact:86-2783341481 18971291927
Address:RM2405 Unit 1 Builing 1, Taiyin Tower, Changqing Road,Wuhan China
HangZhou HuaYe Chemical Technology Co.,Ltd
Contact:+86-13505815007
Address:hangzhou
Shanghai Dano Pharmaceutical Co.,Ld.(expird)
Contact:+86-592-6266840
Address:Building 1 Room 512, 720 Cailun Rd, Zhangjiang High-Tech Park, Shanghai 201203, China
Weifang Adde Economic And Trade Co.,LTD.
Contact:86-536-8885548
Address:Room 1402,Wanda Plaza B Block,No.958,Yuanfei Road,Kuiwen District
SHENYANG COMEBOARD TECHNOLOGY CO., LTD
Contact:+86-24-25724626
Address:Room2210,Tianbao International Building,No.8-1 Weigong South Street,Tiexi District,Shenyang,China
Doi:10.1016/j.tet.2010.01.024
(2010)Doi:10.1007/BF00474046
(1988)Doi:10.1016/j.ica.2009.11.023
(2010)Doi:10.1016/j.bmcl.2010.01.057
(2010)Doi:10.1016/j.bmc.2009.12.066
(2010)Doi:10.1002/anie.200906636
(2010)
