Cyclization of 4-Hydroxy-(E)-2-alkenoic Esters: Simple Synthesis of Butenolides

DOI: 10.1055/s-1986-31659

Source and publish data:

Synthesis p. 416 - 417 (1986)

Update date:2022-08-03

Topics:

Authors:

Tanikaga, Rikuhei

Yamashita, Hiroshi

Kaji, Aritsune

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1055/s-1986-31659

Simple treatment of 4-hydroxy-(E)-2-alkenoic esters with benzenethiol leads to cyclization to give 3-phenylthio-4-alkanolides, which are easily converted into 3-phenylthio-2-alken-4-olides and 2-alken-4-olides (Δ^α,β-butenolides).

Full text of DOI:10.1055/s-1986-31659

Products guided by the article

Product name:5-Hexyl-4-phenylsulfanyl-5H-furan-2-one

Cas No:107323-62-6

R&D Labs maybe for 107323-62-6

Shanghai Dynamic Industrial Co.,Ltd.

website:http://www.shdynamic.com

Contact:86-021 3392 6680

Address:Room 805 Information Tower, No.1403 Minsheng Road, Pudong New Area, Shanghai 200135, P. R. China
SHAANXI TOP PHARM CHEMICAL CO.LTD

Contact:+86-029-85733403

Address:No.108 ,west sector,south er huan,xi'an,china
Suzhou Sinosun Imp.&Exp. Corporation

website:http://www.szsinosun.com

Contact:+86-512-63488895,63488616

Address:No.758 East Jiangling Road Wujiang Economic & Technological Developmenty Zone Jiangsu China
STAR SYNTHESIS CO.,LIMITED

Contact:+(852) 301-98033

Address:Flat C, 23/F, Lucky Plaza, 315-321 Lockhart Road, Wan Chai, Hong Kong
Xi'an Costrong Pharmaceutical Co., Ltd.

Contact:029- 68576496

Address:Room 2004,Shuibao Building,No.190,South Erhuan Rd, Yanta District,Xi'an,Shaan Xi,China

Relevant to this article

Diastereoselective construction of functionalized homoallylic alcohols by Ni-catalyzed diboron-promoted coupling of dienes and aldehydes

Doi:10.1021/ja806113v
(2008)
Efficient preparation of α,α-dialkyl-α-(phenylselanyl) acetates and α,β-unsaturated esters from the corresponding α,α-dialkyl-α-cyanoacetates by a lithium naphthalenide induced reductive selenenylation process

Doi:10.1055/s-2007-990884
(2007)
Formation of a bridging-imido d⁶ rhodium compound by nitrene capture. Insertion and cycloaddition reactions

Doi:10.1021/ic801703d
(2008)
<3,3>-SIGMATROPIC REARRANGEMENT OF SILYL KETENE ACETALS OF METHYL α-(ALLYLOXY)ACETATES.

Doi:10.1016/S0040-4039(00)84311-7
(1986)
Synthesis and characterization of 2,6-di-tert-butyl-1-thio-1,4-benzoquinone, the first isolable monothio-1,4-benzoquinone

Doi:10.1039/b003330h
(2000)
Oxidation of furost-20(22)-enes with 3-chloroperoxybenzoic acid and osmium tetroxide

Doi:10.1135/cccc20011746
(2001)

Article Doi