
Tetrahedron Letters p. 1557 - 1560 (1986)
Update date:2022-08-03
Topics:
Raucher, Stanley
Gustavson, Linda M.
Although the lithium enolate 2a undergoes <2,3>-sigmatropic rearrangement to give 4a, the silyl ketene acetals 3 undergo <3,3>-sigmatropic rearrangement to give 5.This is the first reported <3,3>-sigmatropic rearrangement of a 1,1-dioxy-3-oxa-1,5-diene.
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Doi:10.1080/00397910903219492
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(1986)