Tetrahedron Letters p. 2007 - 2010 (1986)
Update date:2022-09-26
Topics: Addition reaction Workup and Product Isolation Regioselectivity Control
Nozaki, Kyoko
Wakamatsu, Kuni
Nonaka, Tsuyoshi
Tueckmantel, Werner
Oshima, Koichiro
Utimoto, Kiitiro
Treatment of acetylenic compounds with PhMe2SiBEt3Li in the presence of a transition-metal catalyst affords vinylsilanes in good yields.Coexistence of methanol as a proton source is essential for the completion of the reaction.
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