TRANSITION-METAL CATALYZED REGIOSELECTIVE ADDITION OF PhMe2SiBEt3Li AND Bu3SnBEt3Li TO ACETYLENIC COMPOUNDS IN THE PRESENCE OF METHANOL

DOI: 10.1016/S0040-4039(00)84434-2

Source and publish data:

Tetrahedron Letters p. 2007 - 2010 (1986)

Update date:2022-09-26

Topics: Addition reaction Workup and Product Isolation Regioselectivity Control

Authors:

Nozaki, Kyoko

Wakamatsu, Kuni

Nonaka, Tsuyoshi

Tueckmantel, Werner

Oshima, Koichiro

Utimoto, Kiitiro

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Article abstract of DOI:10.1016/S0040-4039(00)84434-2

Treatment of acetylenic compounds with PhMe2SiBEt3Li in the presence of a transition-metal catalyst affords vinylsilanes in good yields.Coexistence of methanol as a proton source is essential for the completion of the reaction.

Full text of DOI:10.1016/S0040-4039(00)84434-2

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