REACTION OF 1-TRIMETHYLSILYLCYCLOPYLLITHIUM DERIVATIVES WITH DICHLOROMETHYL METHYL ETHER. A NOVEL SYNTHESIS OF CYCLOPROPYL SILYL KETONES

DOI: 10.1246/cl.1986.177

Source and publish data:

Chemistry Letters p. 177 - 180 (1986)

Update date:2022-08-04

Topics:

Authors:

Nakajima, Tadashi

Tanabe, Masaru

Ohno, Katsuhiko

Segi, Masahito

Suga, Sohei

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Article abstract of DOI:10.1246/cl.1986.177

Treatment of 1-trimethylsilylcyclopropyllithium derivatives with dichloromethyl methyl ether affords the corresponding new cyclopropyl silyl ketones in moderate yield.This reaction involves the intramolecular 1,2-silicon shift from carbon to carbon.

Full text of DOI:10.1246/cl.1986.177

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