BIOMIMETIC ENTRY TO CHIRAL EPOXIDE SYNTHESIS NOVEL ASYMMETRIC INDUCTION USING CHIRAL ANCHIMERIC ASSISTANCE

DOI: 10.1016/S0040-4039(00)84258-6

Source and publish data:

Tetrahedron Letters p. 1359 - 1362 (1986)

Update date:2022-08-04

Topics:

Authors:

Esaki, Toru

Sakane, Soichi

Yamamoto, Hisashi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)84258-6

Stannic chloride promotes the cyclization of the epoxide 1 at low temperature to give the recovered epoxide in ca. 60percent ee.The result suggests a new evidence for the chiral anchimeric assistance of the olefinic cyclization process.

Full text of DOI:10.1016/S0040-4039(00)84258-6

Products guided by the article

Product name:(R)-2,2-Dimethyl-3-{(E)-3-methyl-5-[(1R,2S,5R)-5-methyl-2-(1-methyl-1-phenyl-ethyl)-cyclohexyloxy]-pent-3-enyl}-oxirane

Cas No:107674-93-1

R&D Labs maybe for 107674-93-1

ZhangJiaGang YaRui Chemical Co.,Ltd.

Contact:0512-58360968

Address:China JiangSu Province Zhang Jia Gang City YangShe Oriental Plaza Building 10 B307
Shanghai Dianyang Industry Co.,ltd

Contact:+86 21 6492 4669

Address:Chejing RD, Songjiang District, Shanghai, China
Luoyang Aoda chemical Co.,Ltd.

Contact:+86-379-67518785 67516588

Address:MiaoWan industry district,YanShi City,Henan,China
Chongqing maohuan Chemicals Co., Ltd

website:http://www.bschem.com

Contact:+86 13996103726

Address:Chongqing Nan'an District Tu Town
Simagchem Corporation

website:http://www.simagchem.com

Contact:+86-592-2680277

Address:21/F Hualong Office Building,No.6 Hubin East Road, Xiamen,China

Relevant to this article

Ti=NR vs Ti-R′ functional group selectivity in titanium imido alkyl cations from an experimental perspective

Doi:10.1021/om800709f
(2008)
Doi:10.1021/jo01175a002
(1946)
Structural characterization of a cationic zirconocene dimethylaniline complex and related catalytically relevant species

Doi:10.1021/om800783h
(2008)
Syntheses of IAA- and IPA-amino acid conjugates

Doi:10.1021/jo8017796
(2008)
Studies on peptides. CXLI. Synthesis of a 42-residue peptide corresponding to the entire amino acid sequence of porcine GIP (Glucose-dependent insulinotropic polypeptide)

Doi:10.1248/cpb.34.3447
(1986)
Furfuryl Cation Induced Cascade Formal [3 + 2] Cycloaddition/Double Ring-Opening/Chlorination: An Approach to Chlorine-Containing Complex Triazoles

Doi:10.1021/acs.orglett.8b03121
(2018)

Article Doi