BIOMIMETIC ENTRY TO CHIRAL EPOXIDE SYNTHESIS NOVEL ASYMMETRIC INDUCTION USING CHIRAL ANCHIMERIC ASSISTANCE

DOI: 10.1016/S0040-4039(00)84258-6

Source and publish data:

Tetrahedron Letters p. 1359 - 1362 (1986)

Update date:2022-08-04

Topics:

Authors:

Esaki, Toru

Sakane, Soichi

Yamamoto, Hisashi

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Article abstract of DOI:10.1016/S0040-4039(00)84258-6

Stannic chloride promotes the cyclization of the epoxide 1 at low temperature to give the recovered epoxide in ca. 60percent ee.The result suggests a new evidence for the chiral anchimeric assistance of the olefinic cyclization process.

Full text of DOI:10.1016/S0040-4039(00)84258-6

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