FORMATION OF REACTIVE TRICYCLIC INTERMEDIATES VIA THE INTRAMOLECULAR CYCLOPROPANATION OF DIHYDROPYRANS. SYNTHESIS OF EUCALYPTOL

DOI: 10.1016/S0040-4039(00)84452-4

Source and publish data:

Tetrahedron Letters p. 2075 - 2078 (1986)

Update date:2022-08-04

Topics:

Authors:

Adams, Julian

Belley, Michel

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Article abstract of DOI:10.1016/S0040-4039(00)84452-4

Tricyclic compound 3 was synthesized via a cyclopropanation reaction promoted by 2.This highly srained compound was found to undergo selective chemical transformations to give <2.2.2> oxa-bicyclic ketones.This methodology was applied in a total synthesis of the monoterpene, eucalyptol.

Full text of DOI:10.1016/S0040-4039(00)84452-4

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