Tetrahedron Letters p. 3091 - 3094 (1986)
Update date:2022-08-05
Topics:
Samuels, William D.
Nelson, David A.
Hallen, Richard T.
The asymmetric reduction of α-aryl ethers 1 was found to be strongly influenced by the presence of ortho substituents on the aryl ring.Groups (methoxy or hydroxy) that chelate metal cations tend to stabilize a "locked" bicyclic 4 which, intermediate when
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