UEBERGANGSMETALL-CARBIN-KOMPLEXE LXXXII. (C6H5)>+-, DARSTELLUNG EINES NEUEN ANIONISCHEN CARBIN-KOMPLEXES DES WOLFRAMS DURCH UMSETZUNG EINES NEUTRALEN CARBIN-KOMPLEXES MIT EINEM ELEKTRONENREICHEN OLEF

DOI: 10.1016/0022-328X(86)80123-1

Source and publish data:

Journal of Organometallic Chemistry p. C13 - C16 (1986)

Update date:2022-07-29

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Authors:

Filippou, Alexander Constantin

Fischer, Ernst Otto

Alt, Helmut Guido

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Article abstract of DOI:10.1016/0022-328X(86)80123-1

The reaction of trans-Br(CO)4WCN(c-C6H11)2 with the electron-rich olefin <=(C6H5)>2 leads to the formation of the new anionic carbyne complex ^-, which was isolated as the (C6H5)>⁺ salt and c

Full text of DOI:10.1016/0022-328X(86)80123-1

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Product name:[HCN(C₆H₅)CH₂CH₂N(C₆H₅)]⁽¹⁺⁾*[Br₂(CO)3WCN(C₆H₁₁)2]^(1-)=[HCN(C₆H₅)C₂H₄N(C₆H₅)][Br₂(CO)3WCN(C₆H₁₁)2]

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